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A schematic and electron microscope cross section shows the structure of an integrated catalyst powered by solar energy to divide water into hydrogen and oxygen fuel. The module developed at Rice University can be directly immersed in water to produce fuel when exposed to sunlight. Credit: Illustration by Jia Liang / Rice University
The concept of “artificial leaf” inspires research at Rice University on the production of fuel with solar energy.
Rice University researchers have created an efficient, low-cost device that divides water to produce hydrogen fuel.
The platform developed by rice materials scientist Jun Lou’s Brown School of Engineering laboratory integrates catalytic electrodes and perovskite solar cells that, when activated by sunlight, produce electricity. Current flows to catalysts that convert water to hydrogen and oxygen, with an efficiency from sunlight to hydrogen of up to 6.7%.
This type of catalysis is not new, but the lab packed a perovskite layer and electrodes in a single module that, when dropped into water and placed in sunlight, produces hydrogen without further input.
The platform presented by Lou, lead author and postdoctoral fellow Rice Jia Liang and colleagues in the American Chemical Society magazine ACS Nano It is a self-sustaining producer of fuel that, they say, should be simple to produce in bulk.
“The concept is broadly similar to an artificial leaf,” said Lou. “What we have is an integrated module that converts sunlight into electricity that drives an electrochemical reaction. It uses water and sunlight to obtain chemical fuels ”.
Perovskites are cube lattice crystals known to harvest light. The most efficient perovskite solar cells produced so far reach an efficiency of over 25%, but the materials are expensive and tend to be stressed by light, humidity and heat.
“Jia has replaced the more expensive components, such as platinum, in perovskite solar cells with alternatives such as carbon,” said Lou. “That lowers the barrier to entry for commercial adoption. Integrated devices like this are promising because they create a system that is sustainable. This does not require any external power supply to keep the module running. “
Liang said the key component may not be perovskite but the polymer that encapsulates it, protecting the module and allowing it to submerge for long periods. “Others have developed catalytic systems that connect the solar cell out of the water with electrodes submerged with a wire,” he said. “We simplify the system by encapsulating the perovskite layer with a Surlyn (polymer) film.”
The patterned film allows sunlight to reach the solar cell while protecting it and serves as an insulator between the cells and the electrodes, Liang said.
“With an intelligent system design, you can potentially do a self-sustaining cycle,” said Lou. “Even when there is no sunlight, you can use the stored energy in the form of chemical fuel. You can put the hydrogen and oxygen products in separate tanks and incorporate another module like a fuel cell to convert those fuels into electricity.”
The researchers said they will continue to improve the encapsulation technique as well as the solar cells themselves to increase the efficiency of the modules.
Reference: “A Low-Cost, High-Efficiency Integrated Device for Solar Energy Water Division” by Jia Liang, Xiao Han, Yunxiu Qiu, Qiyi Fang, Boyu Zhang, Weipeng Wang, Jing Zhang, Pulickel M. Ajayan and Jun Lou , April 29, 2020, ACS Nano.
DOI: 10.1021 / acsnano.9b09053
The article’s co-authors are former Rice visiting students, Xiao Han, now an associate professor at Northwest Polytechnic University in Xi’an, China, and Yunxiu Qiu, now a graduate student at Washington University in St. Louis; Rice graduate students Qiyi Fang and Boyu Zhang; Former Weipeng Wang rice student, now an assistant professor at Tsinghua University; Rice Postdoctoral Researcher Jing Zhang; and Pulickel Ajayan, chairman of Rice’s Department of Materials Science and Nanoengineering, Professor of Engineering Benjamin M. and Mary Greenwood Anderson and professor of chemistry. Lou is a professor of materials science, nanoengineering and chemistry.
The research was funded by the Peter M. and Ruth L. Nicholas Postdoctoral Fellowship in Nanotechnology from the Rice Smalley-Curl Institute, the Welch Foundation, the Nanosystem Engineering Research Center supported by the National Science Foundation for Water Treatment with Nanotechnology and Fundamental Research Funds for central universities, China.
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